Претрага
243 items
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A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties
Single crystals of the new disodium tricopper(II) tetrakis(hydrogenarsenate(V)) tetrahydrate, Na2Cu3(AsO3OH)4·4H2O were grown under hydrothermal conditions. The compound was characterized by room-temperature single-crystal X-ray diffraction, SEM-EDS analysis, Raman spectroscopy and magnetic susceptibility measurements. Na2Cu3(AsO3OH)4·4H2O represents a new layered structure-type [space group P21/c, a = 8.7089(17), b = 9.7452(19), c = 9.3353(19) Å, β = 92.63(3)°, V = 791.4(3) Å3, Z = 4]. The layers are normal to [100] and are composed of the isolated Cu3O12 units interconnected by AsO3OH coordination ...Na2Cu3(AsO3OH)4•4H2O, хидротермална синтеза, кристална структура, хидрирани хидрокси-арсенати, магнетна својстваTamara Đorđević, Ljiljana Karanović, Zvonko Jagličić. "A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties" in Journal of Solid State Chemistry, Elsevier BV (2018). https://doi.org/10.1016/j.jssc.2018.05.024
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Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes
Reakcije supstitucije monofunkcionalnih kompleksa [(TLtBu)PdCl]+ i [Pd(tpdm)Cl]+, gde je TLtBu = 2,6-bis[(1,3-di-terc-butilimidazolin-2-imino)metil]piridin i tpdm = terpiridindimetan, sa nukleofilima kao što su: tiourea, I−, Br−, NO2−, piridin i dimetil-sulfoksid (DMSO) proučavani su u 0,1 M vodenom rastvoru NaClO4 u prisustvu 10 mM NaCl. Reakcije su sprovedene na tri različite temperature (288, 298 i 308 K) korišćenjem tehnike zaustavljenog protoka na različitim temperaturama. Reakcije supstitucije su praćene pod uslovima pseudo prvog reda sa velikim viškom nukleofila. Dobijeni rezultati pokazuju da kompleks ...Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić. "Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes" in Inorganica Chimica Acta, Elsevier BV (2011). https://doi.org/10.1016/j.ica.2011.11.031
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A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra
Tamara Đorđević, Ljiljana Karanović (2010)A new monoclinic polymorph of Ba(AsO3OH) was synthesized under hydrothermal conditions. It represents a previously unknown structure type. Its crystal structure was determined from a racemic twin using single-crystal X-ray diffraction data collected at 120 and 293 K [space group P21, a=7.2149(14)/7.2370(2), b=7.7028(15)/7.7133(2), c=21.7385(43)/21.8079(5) Å, β=95.95(3)/96.073(1)1, V=1201.6(4)/1210.51(5) Å3, Z=12]. The crystal structure of P21-Ba(AsO3OH) has a layered character and is built up of four types of regularly alternating layers parallel to (0 0 1). Every AsO3OH tetrahedron is chelating to two Ba atoms and ...Ba(AsO3OH), хидротермална синтеза, структурна анализа монокристала, Раманска спектроскопија, инфрацрвена спектроскопија, водоничне везе, хидрогенарсенати земноалкалних металаTamara Đorđević, Ljiljana Karanović. "A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra" in Journal of Solid State Chemistry, Elsevier BV (2010). https://doi.org/10.1016/j.jssc.2010.09.027
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Improvement of 1D geoelectric sounding by narrowing the equivalence range and identification, quantification and reduction of lateral effects using the tri-potential technique
Filip Arnaut, Branislav Sretenović, Vesna Cvetkov. "Improvement of 1D geoelectric sounding by narrowing the equivalence range and identification, quantification and reduction of lateral effects using the tri-potential technique" in Geofizika, University of Zagreb, Faculty of Science, Department of Geophysics (2022). https://doi.org/10.15233/gfz.2022.39.15
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Short-term forecasting of PM10 and PM2.5 concentrations with Facebook's Prophet Model at the Belgrade-Zeleno brdo
Filip Arnaut, Vesna Cvetkov, Dragana Đurić, Mileva Samardžić-Petrović. "Short-term forecasting of PM10 and PM2.5 concentrations with Facebook's Prophet Model at the Belgrade-Zeleno brdo" in Geofizika (2023). https://doi.org/10.15233/gfz.2023.40.7
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Ionothermal synthesis and crystal structure of a new organic–inorganic hybrid compound:catena-poly[bis(1-ethyl-3-methylimidazolium) [hepta-μ-bromido-pentacuprate(I)]]
A new organic-inorganic hybrid compound, catena-poly[bis(1-ethyl-3-methylimidazolium) [μ5-bromido-tri-μ3-bromido-tri-μ2-bromido-pentacuprate(I)]], {(C6H11N2)2[Cu5Br7]}n, has been obtained under ionothermal conditions from a reaction mixture containing Ba(OH)2•8H O, Cu(OH)2•2H2O, As2O5 , 1-ethyl-3-methylimidazolium bromide and distilled water. The crystal structure consists of complex [Cu5Br7]2- anions arranged in sinusoidal {[Cu5Br7]2-}n chains running along the a axis, which are surrounded by 1-ethyl-3-methylimidazolium cations. Three of the five unique Br atoms and one of the three Cu(I) atoms occupy special positions with half-occupancy (a mirror plane perpendicular to the b ...кристална структура, органско-неорганско хибридно једињење, бакар(I) бромид, јонотермна синтеза, 1-етил-3-метилимидазолијум бромид, Cu•••Cu интеракцијеLjiljana Karanović, Dejan Poleti, Tamara Đorđević. "Ionothermal synthesis and crystal structure of a new organic–inorganic hybrid compound:catena-poly[bis(1-ethyl-3-methylimidazolium) [hepta-μ-bromido-pentacuprate(I)]]" in Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography (IUCr) (2014). https://doi.org/10.1107/S205322961402172X
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Phase and microstructural study of urinary stones
In this paper we present the phase and morphological characteristics of urinary stones from Serbian patients. The study included for the first time the determination of the phase composition and a statistical analysis of the presence of different types of urinary stones in both men and women in Serbia. The main goal of study was representation of collected data for the first time. For past three years, more than 600 samples were collected from Serbian patients. The phase composition ...бубрежно камење, фазни састав, статистика, рендгенска дифракција праха, скенирајућа електронска микроскопијаMiljana Mirković, Anja Dosen, Suzana Erić, Predrag Vulić, Branko Matović, Aleksandra Rosić. "Phase and microstructural study of urinary stones" in Microchemical Journal, Elsevier BV (2019). https://doi.org/10.1016/j.microc.2019.104429
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Отпад из процеса сагоревања угља као сировина за добијање елемената ретких земаља
Бојан Земљак (2024)Због великог броја индустрија у којима се користе ови ресурси, глобална економија се у великој мери ослања на елементе ретких земаља. Елементи ретких земаља су есенцијална сировина — материјал за развој савремених технологија, али у односу на њихову огромну потражњу, њихово вађење је ограничено и повезано је са значајним утицајима на животну средину. Због њихове ограничене доступности, проблема који се јављају при процесима експлоатације, све више и више земаља почиње да тражи повољније могућности вађења елемената [REE] из секундарних ...... Journa! of environmental management, 224, p.406-413. [106] North, W., 2022. Solar Farrn-Accommodation and Employment Strategy. [107] Jowitt, S.M., Werner, T.T., Weng, Z. and Mudd, G.M., 2018. Recycling of the rare earth elements. Current Opinion in Green and Sustainable Chemistry, 13, p.1-7. ...
... ometallic chemistry of the lanthanoids and alkaline earths (Doctoral dissertation, Monash University). [35] Wang, C., 2023. 7heory and application of rare earth materials. Springer Nature. [36] Dorenbos, P., 2012. A review on how lanthanide impurity levels change with chemistry and structure ...
... 2< x< 0.7), RE= Sc, Y, La, Lu and Gd]. fnorganic Chemistry, 62(6), p.2694-2704. [55] Feltham, H.L. and Brooker, S., 2014. Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing: only one lanthanide ion. Coordinafion Chemistry Reviews, 276, p.1-33. [56] Ahuja, R., Auluck ...Бојан Земљак. Отпад из процеса сагоревања угља као сировина за добијање елемената ретких земаља, 2024
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Actual contamination of the Danube and Sava rivers at Belgrade (2013)
Milan Antonijević, Marija Arsović, Josef Cáslavský, Vesna Cvetković, Predrag Dabić, Mladen Franko, Gordana Ilić, Milena Ivanovic, Nevena Ivanović, Milica Kosovac, Dragana Medić, Slobodan Najdanović, Milica Nikolić, Jovana Novaković, Tatjana Radovanović, Djurdjina Ranić, Bojan Šajatović, Gorica Špijunović, Ivana Stankov, Jelena Tošović, Polonca Trebse, Olivera Vasiljević, Jan Schwarzbauer (2014)rečni sistemi, stanje zagađenja, organski zagađivači, teški metali, skrining analize, non-target screening... Užice, Serbia, 3Faculty of Chemistry, Brno University of Technology, Czech Republic, 4Faculty of Technology and Metallurgy, Faculty of Chemistry, Faculty of Mining and Geology, Technical Faculty in Bor, University of Belgrade, Serbia, 5Laboratory for Environmental Research, University of Nova ...
... ичка школа, Ужице, 3 Faculty of Chemistry, Brno University of Technology, Czech Republic, 4Технолошко–металуршки факултет, Хемијски факултет, Рударско–геолошки факултет, Технички факултет у Бору, Универзитет у Београду, Београд, 5 Laboratory for Environmental Research, University of Nova Gorica ...
... g author on request. Acknowledgement. This publication is the outcome of the TEMPUS project “Moder- nisation of Postgraduate Studies in Chemistry and Chemistry related Programmes” ___________________________________________________________________________________________________________________________ ...Milan Antonijević, Marija Arsović, Josef Cáslavský, Vesna Cvetković, Predrag Dabić, Mladen Franko, Gordana Ilić, Milena Ivanovic, Nevena Ivanović, Milica Kosovac, Dragana Medić, Slobodan Najdanović, Milica Nikolić, Jovana Novaković, Tatjana Radovanović, Djurdjina Ranić, Bojan Šajatović, Gorica Špijunović, Ivana Stankov, Jelena Tošović, Polonca Trebse, Olivera Vasiljević, Jan Schwarzbauer. "Actual contamination of the Danube and Sava rivers at Belgrade (2013)" in Journal of the Serbian Chemical Society, National Library of Serbia (2014). https://doi.org/10.2298/JSC131105014A
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Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima
Aleksandar M. Mijatović, Jovana Bogojeski. "Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima" in Hemijski pregled, Srpsko hemijsko društvo (2017)
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Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)
Jelena Pantić, Vladimir Urbanovich, Vesna Poharc-Logar, Bojan Jokić, Marija Stojmenović, Aleksandar Kremenović, Branko Matović (2014)Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the highpressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 °C, sphene undergoes into phase transition, from room-temperature phase P21/a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the ...Jelena Pantić, Vladimir Urbanovich, Vesna Poharc-Logar, Bojan Jokić, Marija Stojmenović, Aleksandar Kremenović, Branko Matović. "Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)" in Physics and Chemistry of Minerals, Springer Science and Business Media LLC (2014). https://doi.org/10.1007/s00269-014-0693-x
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Atmospheric exposure vs burying: influences on damage intensity of built-in kersantite in the monument of the Small Staircase (Belgrade, Serbia)
Proučavan je efekat „zatrpanog kamena“ na intenzitet procesa degradacije prisutnih na kersantitu koji je ugrađen u spomenik Malo stepenište. Istraživanja su vršena na uzorcima stene iz kamenoloma i na oštećenim kamenim blokovima ugrađenim u spomenik. Dok su neki delovi stepeništa bili pod zemljom 90 godina, većina kamenih elemenata je bila izložena različitim uslovima sredine i antropogenim uticajima. Urađeno je detaljno mapiranje trenutnog stanja spomenika kako bi se istražio uticaj “zatrpavanja” i kompleksne geometrije spomenika na tip propadanja i variranje ...Nevenka Novaković, Predrag Dabić, Vesna Matović. "Atmospheric exposure vs burying: influences on damage intensity of built-in kersantite in the monument of the Small Staircase (Belgrade, Serbia)" in Environmental Earth Sciences, Springer Science and Business Media LLC (2023). https://doi.org/10.1007/s12665-023-10794-6
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The influence of rainfall factors on soil resistance to erosion
Nikola Živanović, Vukašin Rončević, Carla Ferreira, Milica Kašanin-Grubin, Stevan Ćorluka, Veljko Rupar, Vladimir Čebašek (2024)Nikola Živanović, Vukašin Rončević, Carla Ferreira, Milica Kašanin-Grubin, Stevan Ćorluka, Veljko Rupar, Vladimir Čebašek. "The influence of rainfall factors on soil resistance to erosion" in EGU General Assembly 2024, Vienna, Austria, Apr 14–19, 2024, Copernicus GmbH (2024). https://doi.org/10.5194/egusphere-egu24-1137
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Sinteza i karakterizacija vanadata alkalnih metala sa elementima retkih zemalja
Anđela Jovanović (2024)Predmet i cilj pisanja ovog rada su sinteza i karakterizacija vanadata alkalnih metala sa elementima retkih zemalja. Prilikom ovih istraživanja, ispitivan je sistem REE2O3–V2O5–KF, gde REE predstavlja trovalentni katjon izabranih elemenata retkih zemalja (Y, Sm, Eu, Gd, Er, Yb). Ovo istraživanje bazirano je na sintezi kristala, nakon čega su dobijeni kristali posmatrani pod binokularnom lupom, analizirani metodom rendgenske difrakcije na polikristalnom materijalu (XRPD) i metodom skenirajuće elektronske mikroskopije sa energetsko-disperzivnom spektroskopijom (SEM-EDS), kako bi se utvrdile karakteristike dobijenih kristala. ...elementi retkih zemalja, sinteza kristala metodom fluksa, vanadati alkalnih metala, rendgenska difrakcija, SEM-EDS metodaAnđela Jovanović. Sinteza i karakterizacija vanadata alkalnih metala sa elementima retkih zemalja, 2024
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Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)
Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik (2023)The behaviour and stability of arsenopyrite largely depend on its crystal structure, but studies of crystallography and structural defects are scarce. For clarification, we investigated a series of natural arsenopyrite crystals from the polymetallic Pb-Zn-(±Cu,Ag,Au,Sb,Bi,W) Šumadija-Kopaonik ore district (Serbia) by powder X-ray diffraction (XRPD). Among them, samples from the Drenjak gold mineralisation showed near-stoichiometric FeAsS composition and were further investigated by conventional and high-resolution transmission electron microscopy methods. TEM revealed abundant planar crystallographic defects and epitaxial surface oxide layer ...Inorganic Chemistry, Condensed Matter Physics,General Materials Science, General Chemical Engineering, crystal structure, FeAsS, oxidation, TEM, XRPD... also one of the main natural sources of arsenic in environmental geochemistry, presenting, potential ecological concerns due to As release through sulphide weathering and oxidation. The existing, research on arsenopyrite mainly focuses on the chemistry, processing, and weathering of the Au-containing ...
... arsenopyrite crystal structure. Conflicts of Interest: The authors declare no conflict of interest. References 1. · Vaughan, D.J.;Craig, J. Mineral Chemistry of Metal Sulfides; Cambridgjee University Press: Cambridge, UK, 1978. 2. · Merkulova, M.; Mathon, O.; Glatzel, P.; Rovezzi, M.; Batanova, V.; Marion ...
... fundamental work on the prototype arsenopyrite structure and have further implications for studies on ion incorporation into FeAsS structure and its environmental stability and oxidation mechanisms as a source of anthropogenic As release into the environment. Keywords: FeAsS; crystal structure; oxidation; ...Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik. "Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)" in Crystals, MDPI AG (2023). https://doi.org/10.3390/cryst13020278
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Characterization of Natural Clay from Bogovina (Serbia) and Possible Utilization in Sorption of the Herbicides
... Đurović-Pejčev2, Maja Milošević3 1Department for Soil Management, Faculty of Agriculture/ University of Belgrade, 2Laboratory of Chemistry, Institute of pesticides and environmental protection, 3Department of Geology, Faculty of Mining and Geology, Belgrade, Serbia Presentation Preference: Poster only Would ...Lazar Kaluđerović, Zorica Tomić, Rada Đurović-Pejčev, Maja Milošević. "Characterization of Natural Clay from Bogovina (Serbia) and Possible Utilization in Sorption of the Herbicides" in Eurosoil2020, online event 2021, Eurosoil, Frontiers Abstract Book (2021)
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The use of biological markers in determination of origin and type of organic matter in the Tisza river sediments
Snežana Štrbac, Gordana Gajica, Aleksandra Šajnović, Nebojša Vasić, Ksenija Stojanović, Branimir Jovančićević (2013)The objective of the study was to determine the origin and type of organic matter (OM) of the Tisza recent sediments along the distance of 153 km through the territory of Serbia. For this purpose group organic-geochemical parameters and biomarker compositions were used. All samples contain approximately same amount of OM, which was deposited under uniform, slightly reducing conditions. Based on the distribution of n-alkanes, the origin and type of OM could not be precisely estimated. However, n-alkane patterns ...... NEBOJŠA VASIĆ3, KSENIJA STOJANOVIĆ4*# and BRANIMIR JOVANČIĆEVIĆ4# 1Faculty of Environmental Protection, University EDUCONS, Vojvode Putnika 87, 21207 Sremska Kamenica, Serbia, 2University of Belgrade, ICTM, Center of Chemistry, Njegoševa 12, 11000 Belgrade, Serbia, 3University of Belgrade, Faculty of ...
... polycyclic alkanes of the ste- rane and terpane types and alkylaromatics have been used. Recently, the appli- cation of biological markers in environmental chemistry has proved its self to be a promising tool for the determination and identification of petroleum pollutants in soils, recent sediments, ground ...
... relative length of migration and mineral composition of the source and reservoir rocks.10,11 This feature of oil can be very useful in environmental chemistry for the determination of the source of pollution. Consequently, analyses of this type obtain a forensic character. In this paper, the ...Snežana Štrbac, Gordana Gajica, Aleksandra Šajnović, Nebojša Vasić, Ksenija Stojanović, Branimir Jovančićević. "The use of biological markers in determination of origin and type of organic matter in the Tisza river sediments" in Journal of Serbian Chemical Society, Beograd : Srpsko hemijsko društvo (2013). https://doi.org/10.2298/JSC130614087S
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Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes
Goran Marković, Aleksandar Ž. Kostić, Nebojša Đ. Pantelić, Radojka Maletić, Jana Štrbački, Jovan Cakić, Lazar Kaluđerović, Biljana P. Dojčinović, Angelo Maria Giuffrè, Jelena B. Popović-Djordjević (2023)Lakes and reservoirs are the main water resources for household, irrigation, and industrial use. Hence, it is necessary to control water pollution and have reliable information on water quality, which refers to its suitability for a particular purpose. The main objective of this study was to evaluate the suitability of water for drinking and irrigation purposes from ten artificial lakes on the territory of the Republic of Serbia. The physicochemical parameters were determined using standard analytical methods, whereas the ...Goran Marković, Aleksandar Ž. Kostić, Nebojša Đ. Pantelić, Radojka Maletić, Jana Štrbački, Jovan Cakić, Lazar Kaluđerović, Biljana P. Dojčinović, Angelo Maria Giuffrè, Jelena B. Popović-Djordjević. "Spatial distribution of major and trace elements in artificial lakes in Serbia: health risk indices and suitability of water for drinking and irrigation purposes" in Environmental Monitoring and Assessment, Springer Science and Business Media LLC (2023). https://doi.org/10.1007/s10661-023-11740-6
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Design of the Opencast Coal Mine Drmno Dewatering System
Development of mining in the opencast mine Drmno from Kostolac basin in Serbia is carried out in the increasingly complex geological and hydro geological conditions with the decline of the coal seams to the alluvial part of Europe's largest river Danube. Greater depth and inflow of groundwater significantly increase costs for dewatering facilities construction with the requirement for optimizing of this more and more important surface mining process. Making decision on screen construction in the opencast mine with redesign ...dewatering system, groundwater, hydrodynamic model, dewatering wells, screen, reliability, environmental effects.Vladimir Pavlović, Dušan Polomčić, Tomislav Šubaranović. "Design of the Opencast Coal Mine Drmno Dewatering System" in Proceedings of the 12th International Symposium Continuous Surface Mining - Aachen 2014, Springer International Publishing (2014). https://doi.org/10.1007/978-3-319-12301-1_11
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Environmental Noise Impact Assessment for Large-Scale Surface Mining Operations in Serbia
Noise emissions are a significant environmental impact caused by the mining industry in all technological phases of surface mining, mineral processing, and waste disposal. This paper presents the role of noise impact assessment and control in large-scale surface mining operations. Mine planning develops the model of mining operations, ore excavation, and waste dumping scheduling and processing rates, including spatial distribution of mining activities. Such a level of mine planning requires an environmental impact assessment study. This can be achieved ...Uros Pantelic, Petar Lilic, Aleksandar Cvjetic, Nikola Lilic. "Environmental Noise Impact Assessment for Large-Scale Surface Mining Operations in Serbia" in Sustainability, MDPI AG (2023). https://doi.org/10.3390/su15031798