Devolatilization behaviour of Kolubara and Kostolac lignite (Serbia) during the combustion process: A case study

Објеката

Тип
Рад у часопису
Верзија рада
објављена верзија
Језик
енглески
Креатор
Miodrag Životić, Nenad Nikolić, Dragoslava Stojiljković, Danica Bajuk-Bogdanović, Dragana Životić
Извор
International Journal of Coal Geology
Издавач
Elsevier BV
Датум издавања
2024
Сажетак
In this study the devolatization behaviour of lignite samples, of various grain sizes, on a wire mesh reactor is evaluated. Lignite samples were rapidly heated at four different temperatures (300, 500, 700 and 900 ◦C). The feed lignite reveals a high content of huminite, a low inertinite and liptinite contents in the Kostolac samples and a slightly higher liptinite content in the Kolubara samples. The char obtained at 300 ◦C and 500 ◦C shows slight petrographic and chemical changes. The major changes in chemical and petrographic compositions were observed in char heated at higher temperatures (700 ◦C and 900 ◦C). FTIR spectral data for both Kolubara and Kostolac lignite samples reveal a decrease in aliphatic- and oxygen-containing structures with increase in temperatures from 300 to 700◦C. The lack of aliphatic and oxygen-containing structures, the breakdown of clay minerals and negligible amount of water are detected in samples devolatilized at 900 ◦C where aromatic structures dominate.
Huminite reflectance of initial samples confirms the low rank (lignite) of all the samples. Char of all grain sizes obtained at 300◦C and 500◦C showed very small changes in the maceral composition and reflectance value and still corresponded to lignite rank. A significant change in maceral composition and increase reflectance is observed in char obtained at 700 ◦C and 900 ◦C of all grain sizes.
том
295
Број
104641
број страница
20
doi
10.1016/j.coal.2024.104641
issn
0166-5162
Subject
деволатилизација, реактор жичане мреже, петрографски састав, Колубарски и Костолачки басен
devolatilization, wire mesh reactor, petrographic composition, Kolubara and Kostolac Basins
Шира категорија рада
M20
Ужа категорија рада
М21а
Права
Затворени приступ
Лиценца
All rights reserved
Формат
.pdf
isbn
Miodrag Životić
Nenad Nikolić
Dragoslava Stojiljković
Danica Bajuk-Bogdanović
Драгана Животић
Скупови објеката
Radovi istraživača

Miodrag Životić, Nenad Nikolić, Dragoslava Stojiljković, Danica Bajuk-Bogdanović, Dragana Životić. "Devolatilization behaviour of Kolubara and Kostolac lignite (Serbia) during the combustion process: A case study" in International Journal of Coal Geology, Elsevier BV (2024). https://doi.org/10.1016/j.coal.2024.104641 М21а

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