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388 items
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Ionothermal synthesis and crystal structure of a new organic–inorganic hybrid compound:catena-poly[bis(1-ethyl-3-methylimidazolium) [hepta-μ-bromido-pentacuprate(I)]]
A new organic-inorganic hybrid compound, catena-poly[bis(1-ethyl-3-methylimidazolium) [μ5-bromido-tri-μ3-bromido-tri-μ2-bromido-pentacuprate(I)]], {(C6H11N2)2[Cu5Br7]}n, has been obtained under ionothermal conditions from a reaction mixture containing Ba(OH)2•8H O, Cu(OH)2•2H2O, As2O5 , 1-ethyl-3-methylimidazolium bromide and distilled water. The crystal structure consists of complex [Cu5Br7]2- anions arranged in sinusoidal {[Cu5Br7]2-}n chains running along the a axis, which are surrounded by 1-ethyl-3-methylimidazolium cations. Three of the five unique Br atoms and one of the three Cu(I) atoms occupy special positions with half-occupancy (a mirror plane perpendicular to the b ...кристална структура, органско-неорганско хибридно једињење, бакар(I) бромид, јонотермна синтеза, 1-етил-3-метилимидазолијум бромид, Cu•••Cu интеракцијеLjiljana Karanović, Dejan Poleti, Tamara Đorđević. "Ionothermal synthesis and crystal structure of a new organic–inorganic hybrid compound:catena-poly[bis(1-ethyl-3-methylimidazolium) [hepta-μ-bromido-pentacuprate(I)]]" in Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography (IUCr) (2014). https://doi.org/10.1107/S205322961402172X
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Paragenetske karakteristike i geneza rudnih pojava Pb-Zn i Cu u rejonuKonjuha| SR Crna Gora
Mileta Duvbak (1977)Mileta Duvbak. Paragenetske karakteristike i geneza rudnih pojava Pb-Zn i Cu u rejonuKonjuha| SR Crna Gora, Beograd:Rudarsko-geološki fakultet, 1977
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Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands
A series of novel ternary Co(II), Ni(II) and Cu(II) complexes containing 2,20-dipyridylamine (dipya), 2,20-bipyridine (bipy), and 1,10-phenanthroline (phen), as aromatic diamine ligands, and dianion of isophthalic acid (ipht) have been prepared by ligand exchange reactions from diluted H2O/EtOH solutions. The complexes were characterized by elemental analysis, IR spectroscopy, magnetic susceptibility measurements and TG and DSC analysis. Three complexes, Cu(dipya)(ipht)H2O (1), Co(dipya)(ipht)2H2O (2) and Cu(ipht)(phen)2H2O (5) are polymeric with bis-monodentate ipht, while the other two complexes M(bipy)(ipht)4H2O, M@Co(II) (3) and ...комплекси прелазних метала, карбоксилатни лиганди, N-лиганди, кристална структура, магнетна својстваJelena Rogan, Dejan Poleti, Ljiljana Karanović, Zvonko Jagličić. "Synthesis, magnetic, thermal and structural properties of Co(II), Ni(II) and Cu(II) complexes containing isophthalato ligands" in Journal of Molecular Structure, Elsevier BV (2011). https://doi.org/10.1016/j.molstruc.2010.11.024
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Synthesis of MnCo2O4 nanoparticles as modifiers for simultaneous determination of Pb(II) and Cd(II)
The porous spinel oxide nanoparticles, MnCo2O4, were synthesized by citrate gel combustion technique. Morphology, crystallinity and Co/Mn content of modified electrode was characterized and determined by Fourier transform infra-red spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction pattern analysis (XRD), simultaneous thermogravimetry and differential thermal analysis (TG/DTA). Nanoparticles were used for modification of glassy carbon electrode (GCE) and new sensor was applied for simultaneous determination of Pb(II) and Cd(II) ions in water samples with the ...Vesna Antunović, Marija Ilić, Rada Baošić, Dijana Jelić, Aleksandar Lolić. "Synthesis of MnCo2O4 nanoparticles as modifiers for simultaneous determination of Pb(II) and Cd(II)" in PLOS ONE (2019). https://doi.org/10.1371/journal.pone.0210904
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Cytotoxic activity of tetradentate Schiff Base Copper(II) complexes
Istraživanje kompleksa bakra kao potencijalnih antikancerogenih agenasa nudi ohrabrujuće perspektive u odnosu na komplekse platine (II) računajući na smanjenu toksičnost, novi mehanizam delovanja, različit spektar aktivnosti i perspektivu neunakrsne rezistencije. Kompleksi Šifovih baza bakra(II) koji sadrže tetradentatne ligande acac2en tipa (acac2en (1); tfacac2en (3), acactfacacen (4), acacphacacen (6)) pokazali su važnu antioksidativnu aktivnost, visok potencijal za interakciju sa HSA i DNK, u prethodnim studijama. Zbog toga je bilo interesantno ispitati i uporediti potencijal antikancerogene aktivnosti in vitro, u odnosu ...Nevenka Gligorijević, Aleksandar Mijatović, Sandra Aranđelović, Rada Baošić . "Cytotoxic activity of tetradentate Schiff Base Copper(II) complexes" in The European Association for Cancer Research 2021 , eacr2021.org/sponsorship (2021)
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Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima
Aleksandar M. Mijatović, Jovana Bogojeski. "Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima" in Hemijski pregled, Srpsko hemijsko društvo (2017)
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Distribution of major and trace elements in the Kovin lignite (Serbia)
Dragana Životić, Olga Cvetković, Predrag Vulić, Ivan Gržetić, Vladimir Simić, Konstantin Ilijević, Biljana Dojčinović, Suzana Erić, Bogdan Radić, Sanja Stojadinović, Snežana Trifunović (2019)geochemical and mineralogical study was performed on lignite samples from the Upper Miocene Kovin deposit, hosting three coal seams. The Kovin lignite is characterized by high moisture content, medium to high ash yield, medium to high sulphur content and a relatively low gross and net calorific value. The mineralogical composition, and major and trace element contents were determined by X-ray diffraction, scanning electron microscopy with energy dispersive Xray spectroscopy (SEM-EDS) analyses, and inductively coupled plasma optical emission spectrometry (ICP-OES). ...... Seam As Ba Cd Co Cr Cu Ga Li Mo Ni Pb 2/79 II 29.5 43.5 1.5 6.4 52.2 21.7 3.2 9.5 4.0 65.1 24.3 3/79 II 30.3 122.7 2.4 16.9 125.3 69.0 19.8 84.8 7.4 83.2 80.2 4/79 II 33.6 72.6 1.5 26.3 65.6 24.6 7.0 17.3 5.4 73.4 31.8 5/79 II 4.3 9.3 0.2 3.4 8.4 3.1 0.9 2.2 0.7 9.4 4.1 6/79 II < 0.5 170.3 1.4 9.4 ...
... Tm, Lu (in the seam I); Fe, K, Na, Pb, Th, Sm, Eu, Ho, Yb, Lu (in the seam II) and Li, V, La, Pr, Nd, Dy, Y (in the seam III). Some elements, such as Mg, Mn, As, Cu, Zn and Pb, in seam I; Mo, Zn, in seam II; Mg, Co, Cu, Mo, Pb, Rb, Se, in seam III, have mixed affinities with Figure 5. Macrope ...
... (Serbia) 77 Table S-VII. Continuied. I seam II seam III seam Al affinity rAl= 0.7–1.0 Si (0.78), Ti (0.87), Cu (0.85), Ga (0.86), Li (0.94), Sc (0.79), Th (0.81), V (0.73), Gd (0.76), Tb (0.85). Si (0.88), Ti (0.84), K (0.74), Ba (0.86), Cr (0.75), Cu (0.86), Ga (0.86), Li (0.90), Pb (0.74), Sc ...Dragana Životić, Olga Cvetković, Predrag Vulić, Ivan Gržetić, Vladimir Simić, Konstantin Ilijević, Biljana Dojčinović, Suzana Erić, Bogdan Radić, Sanja Stojadinović, Snežana Trifunović. "Distribution of major and trace elements in the Kovin lignite (Serbia)" in Geologia Croatica, Croatian Geological Survey (2019). https://doi.org/10.4154/gc.2019.06
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Antioxidant and antimicrobial activity of some tetradentate Schiff bases and their Cu (II) complexes
Aleksandar Mijatović, Milan Nikolić, Snežana Spasić, Aleksandra N. Žerađanin, Kristina Joksimović, Aleksandar Lolić, Rada Baošić (2020)Šifove baze i njihovi Cu(II) kompleksi su poznati po svojoj biološkoj aktivnosti. U ovom radu proučavana je antibakterijska aktivnost protiv gram-negativnih sojeva Escherichia coli, Pseudomonas aeruginosa i Staphilococcus piogenes, kao i Gram-pozitivnih Staphilococcus piogenes i Pseudomonas aeruginosa, zajedno sa antifungalnim dejstvom protiv Musperg strainilusa, A. Takođe, tehnički jednostavni i brzi testovi kao što su ABTS, HORAC i ORAC korišćeni su za ispitivanje antioksidativne aktivnosti kako bi se uporedili dobijeni rezultati sa različitim tipovima testova. Uprkos tome što je princip ...Aleksandar Mijatović, Milan Nikolić, Snežana Spasić, Aleksandra N. Žerađanin, Kristina Joksimović, Aleksandar Lolić, Rada Baošić. "Antioxidant and antimicrobial activity of some tetradentate Schiff bases and their Cu (II) complexes" in XIII Conference of Chemists, Technologists and Environmentalists of Republic of Srpska, University in Banjaluka, Faculty of Technology (2020)
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The interaction of organoselenium trans-palladium(II) complexes toward small-biomolecules and CT-DNA
Serija organoselenijum trans-paladijum(II) kompleksa 1 (bis(2-(fenilselanilmetil)oksolan)dihloropaladijum(II)), 2 (bis(2-(fenilselanilmetil)oksan)dihloropaladijum(II)) i 3 (bis(2) ,2-dimetil-3-(fenilselanil)oksan)dihloropaladijum(II)) su korišćeni za ispitivanje reaktivnosti ovog specifičnog tipa kompleksa prema različitim bio-molekulima. Ovaj sistem je od posebnog interesa jer se jako malo zna o supstitucionim reakcijam organoselenijum paladijum(II) kompleksa sa trans konfiguracijom. Zamena koordinovanog hlorida sa serijom malih bio-molekula (l-Met, l-His, l-Cis, GSH i 5′-GMP) proučavana je pod uslovima pseudo-prvog reda kao funkcija koncentracije nukleofila i temperature korišćenjem tehnika zaustavljenog toka. Rezultati za proučavane komplekse ukazuju da ...Vera M. Divac, Aleksandar Mijatović, Marina D. Kostić, Jovana Bogojeski. "The interaction of organoselenium trans-palladium(II) complexes toward small-biomolecules and CT-DNA" in Inorganica Chimica Acta, Elsevier BV (2017). https://doi.org/10.1016/j.ica.2017.07.012
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Barium nickel(II) diarsenate, BaNiAs2O7 - Баријум-бакар(II)-диарсенат, BaNiAs2O7
Kovač Sabina, Karanović Ljiljana, Wittwer Astrid, Đorđević Tamara. "Barium nickel(II) diarsenate, BaNiAs2O7 - Баријум-бакар(II)-диарсенат, BaNiAs2O7" in XXI Konferencija Srpskog kristalografskog društva, Izvodi radova, Užice, Srbija:Srpsko kristalografsko društvo (2014): 70-71
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Kinetics and the mechanism of the supstitution reactions of some Pt(II) and Pd(II) complexes
Bogojeski Jovana, Mijatović Aleksandar, Đurović Mirjana, Petrović Biljana, Bugarčić D. Živadin (2011)Bogojeski Jovana, Mijatović Aleksandar, Đurović Mirjana, Petrović Biljana, Bugarčić D. Živadin. "Kinetics and the mechanism of the supstitution reactions of some Pt(II) and Pd(II) complexes" in First EuCheMS Inorganic Chemistry Conference, University of Manchester, UK (2011): 11-14
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DNA/BSA interactions and cytotoxic studies of tetradentate N,N,O,O Schiff base copper(II) complexes
Aleksandar Mijatović, Angelina Caković, Aleksandar Lolić, Snezana Sretenović, Marko Živanović, Dragana Seklić, Jovana Bogojeski, Biljana Petrović (2023)Three Schiff base Cu(II) complexes, (N,N’-bis(acetylacetone)propylenediimine)copper(II) complex, [Cu(acac2pn)] (1), (N,N'-bis-(benzoylacetone)propylenediimine)copper(II) complex, [Cu(phacac2pn)] (2) and (N,N’-bis-(trifluoroacetylacetone)propylenediimine)copper(II) complex, [Cu(tfacac2pn)] (3), were used to investigate the interactions with calf thymus DNA (ct-DNA) and bovine serum albumin (BSA) using the electronic absorption and spectroscopic fluorescence methods. UV-Vis absorption studies showed that studied complexes interact with DNA molecule and exhibit moderate binding affinity. Fluorescence studies of complexes 1-3 also showed a possibility for DNA intercalation as well as a relatively high binding ability ...Aleksandar Mijatović, Angelina Caković, Aleksandar Lolić, Snezana Sretenović, Marko Živanović, Dragana Seklić, Jovana Bogojeski, Biljana Petrović. "DNA/BSA interactions and cytotoxic studies of tetradentate N,N,O,O Schiff base copper(II) complexes" in Journal of the Serbian Chemical Society (2023). https://doi.org/10.2298/JSC230614063M
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Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes
Reakcije supstitucije monofunkcionalnih kompleksa [(TLtBu)PdCl]+ i [Pd(tpdm)Cl]+, gde je TLtBu = 2,6-bis[(1,3-di-terc-butilimidazolin-2-imino)metil]piridin i tpdm = terpiridindimetan, sa nukleofilima kao što su: tiourea, I−, Br−, NO2−, piridin i dimetil-sulfoksid (DMSO) proučavani su u 0,1 M vodenom rastvoru NaClO4 u prisustvu 10 mM NaCl. Reakcije su sprovedene na tri različite temperature (288, 298 i 308 K) korišćenjem tehnike zaustavljenog protoka na različitim temperaturama. Reakcije supstitucije su praćene pod uslovima pseudo prvog reda sa velikim viškom nukleofila. Dobijeni rezultati pokazuju da kompleks ...... for the substitution reactions of the Pd(II) complexes. Comparing the reactivity of the nucleophiles we observed that the reactivity decreases in the following order: thiourea > I� > Br� > NO2 � > pyridine > DMSO. It is generally known that the Pt(II) and Pd(II) complexes have a very high affinity towards ...
... for the substitution reactions of the Pd(II) complexes. Comparing the reactivity of the nucleophiles we observed that the reactivity decreases in the following order: thiourea > I” > Br- > NO” > pyridine > DMSO. It is generally known that the Pt(II) and Pd(II) complexes have a very high affinity towards ...
... hindered monofunctional Pd(II) complexes Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić Дигитални репозиторијум Рударско-геолошког факултета Универзитета у Београду [ДР РГФ] Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes | Aleksandar ...Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić. "Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes" in Inorganica Chimica Acta, Elsevier BV (2011). https://doi.org/10.1016/j.ica.2011.11.031
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A series of nickel(ii) thiocyanate complexes comprising various molar contents of isonicotinamide and water as ligands or co-crystallized moieties – an experimental and computational study
Lucija Hok, Robert Vianello, Dubravka Matković-Čalogović, Ljiljana Karanović, Sunčica Roca, Jarosław Jaźwiński, Marina Tašner, Darko Vušak, Marijana Đaković, Zora Popović (2022)Lucija Hok, Robert Vianello, Dubravka Matković-Čalogović, Ljiljana Karanović, Sunčica Roca, Jarosław Jaźwiński, Marina Tašner, Darko Vušak, Marijana Đaković, Zora Popović. "A series of nickel(ii) thiocyanate complexes comprising various molar contents of isonicotinamide and water as ligands or co-crystallized moieties – an experimental and computational study" in CrystEngComm, Royal Society of Chemistry (RSC) (2022). https://doi.org/10.1039/d2ce00847e
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Грешка инклинације код депозиционе реманетне магнетизације
Mirko Petković, Vesna Cvetkov (2019)... available in open access, as well as the employees' publications. - The Repository is available at: www.dr.rgf.bg.ac.rs II KONGRES GEOLOGA BOSNE I HERCEGOVINE SA MEĐUNARODNIM UČEŠĆEM II КОНГРЕС ГЕОЛОГА БОСНЕ И ХЕРЦЕГОВИНЕ СА МЕЂУНАРОДНИМ УЧЕШЋЕМ 314 GREŠKA INKLINACIJE KOD DEPOZICIONE REMANENTNE ...
... elipticiteta zrna, f, zavisnog od mjerenih vrijednosti anizotropije anhisterezisne remanentne magnetizacije uzorka. II KONGRES GEOLOGA BOSNE I HERCEGOVINE SA MEĐUNARODNIM UČEŠĆEM II КОНГРЕС ГЕОЛОГА БОСНЕ И ХЕРЦЕГОВИНЕ СА МЕЂУНАРОДНИМ УЧЕШЋЕМ 315 Presječna tačka y-ose i prave koja najbolje aproksimira ...
... factor, f, which is dependent on the measured values of the anisotropy of anhysteretic remanent magnetization is II KONGRES GEOLOGA BOSNE I HERCEGOVINE SA MEĐUNARODNIM UČEŠĆEM II КОНГРЕС ГЕОЛОГА БОСНЕ И ХЕРЦЕГОВИНЕ СА МЕЂУНАРОДНИМ УЧЕШЋЕМ 316 calculated. The intersection point of the y-axis ...Mirko Petković, Vesna Cvetkov. "Грешка инклинације код депозиционе реманетне магнетизације" in II Когрес геолога Босне и Херцеговине са међународним учешћем , Удружење геолога у Босни и Херцеговини (2019)
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Heavy metals in lignite and soil of Kostolac-Kovin coal basin, eastern Serbia - comparative analysis with selected cities in Serbia, region, Europe and world
Bogoljub Vučković, Bojan Dimitrijević (2023)The Kostolac-Kovin coal basin with an area of 320 km2, with 5 separate layers of coal and with a total of about 5.7 Bt of geological resources and reserves represents an exceptional potential for coal production in Serbia. The coal resources listed in this way are not fully exploitable, but they represent potential for consideration. In this paper, we deal with the geochemical characteristics of coal seams and perform a comparative analysis of coal affectation on the environment. With ...... Kovin 2 Open Pit Drmno under running II Coal Layer Pb avg. = 20 ppm , III Coal Layer Pb avg. = 12.5 ppm a _— — _ m ——— R K a ___ _— ___— K r — — — _— ——— E e= | CoalLayer | e= MM CoalLayer | el MM CoalLayer || Cu avg. = 60 ppm m Cu avg. = 45 ppm m —. Cu avg. = 40 ppm m eosod| Open Pit Drmno ...
... Figure 7. Presentation of the content of Zn, Pb and Cu in the urban, recreational and industrial top soil in the cities of the region; yellow – I, II and II Kostolac coal, black - the most polluted soil Figure 7 shows that the contents of Zn, Pb, Cu in the top soil in the cities of the region behave ...
... RUDNIK Hall Pioneer, BELGRADE Rudnik 2, RUDNIK II Coal, KOSTOLAC Battery Industry, SOMBOR | Urbancenter,ELGRADE Ada Ciganlija, BELGRADE | __New Belgrade, BELGRADE 'Cu Smelting plant, BOR Oil Rafinery, PANCEVO Figure 6. Content of Zn, Pb and Cu in urban, recreational and industrial top soil in ...Bogoljub Vučković, Bojan Dimitrijević. "Heavy metals in lignite and soil of Kostolac-Kovin coal basin, eastern Serbia - comparative analysis with selected cities in Serbia, region, Europe and world" in 9th International Conference Mining and Environmental Protection, 24–27. May 2023, Sokobanja, Beograd : Univerzitet u Beogradu, Rudarsko-geološki fakultet (2023)
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The influence of structural modification of Pd(II) pincer-type complexes on the kinetics of substitution reactions
Snežana Jovanović Stević, Snežana Radisavljević, Aleksandar Mijatović, Biljana Petrović, Ana Kesić (2023)This mini-review summarizes the kinetic data obtained for the substitution reactions of some palladium(II) complexes containing bis-pyrazolylpyridine derivatives as pincer-type ligands with biologically significant nitrogen- and sulfur-donor biomolecules as nucleophiles. Three structurally different palladium(II) complexes were selected: [Pd(L1)Cl]+ (Pd1), [Pd(L2)Cl]+ (Pd2) and [Pd(L3)Cl]+ (Pd3) (where L1 = bis(2-(1H-pyrazol-1-yl)ethyl)amine, L2 = 2,6-bis(5-(tert-butyl)-1H-pyrazol-3-yl)pyridine, and L3 = 2,6-bis(5-(tert-butyl)-1-methyl-1H-pyrazol-3-yl)pyridine, while for the entering nucleophiles were used thiourea (Tu), L-methionine (L-met), and guanosine-5’-monophosphate (5’-GMP). Kinetic measurements were carried out for all systems as pseudo-first ...Snežana Jovanović Stević, Snežana Radisavljević, Aleksandar Mijatović, Biljana Petrović, Ana Kesić. "The influence of structural modification of Pd(II) pincer-type complexes on the kinetics of substitution reactions" in 2nd International Conference on Chemo and BioInformatics ICCBIKG 2023, 28-29 September 2023, Institute for Information Technologies, University of Kragujevac, Serbia, Kragujevac : Institute for Information Technologies, University of Kragujevac (2023)
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Eksploatacioni učinci ugljenih sistema na površinskom kopu Tamnava–Zapadno polje
U radu su analizirani eksploatacioni učinci ugljenih sistema na površinskom kopu Tamnava–Zapadno polje. Period analize je prvih šest meseci tekuće godine. Analiza je vršena sa aspekta ostvarene proizvodnje, kvaliteta uglja, efektivnog vremena rada, kapacitetnog i vremenskog iskoršćenja i zastoja sistema. Za poređenje podataka različitih parametara koji po svojoj prirodi nisu međusobno uporedivi, u radu su korišćene metode višekriterijumskog odlučivanja.... ||,,...,..., ijijjn MAXMIN AvjKivjKvvvv ii + æöæö =ÎÎ= ç÷ç÷ èøèø 2 1 () n ijj j Sivv ++ = =- å { } ''' 12 ||,,...,..., ijijjn MINMAX AvjKivjKvvvv ii - æöæö =ÎÎ= ç÷ç÷ èøèø 2 1 () n ijj j Sivv -- = =- å 1 , 00 i i ii S CC SS - -+ =££ + ...
... Sistem Sj Rj I BTD 0,31 0,00 II BTD 0,00 1,00 III BTD 1,00 1,00 IV BTD 0,49 0,00 Tabela 4.2 Vrednosti Qj za v = 0,5; 0,6 i 0,7 Sistem v = 0,5 v = 0,6 v = 0,7 Qj Rang Qj Rang Qj Rang I BTD 0,153015 1 0,183619 1 0,214222 1 II BTD 0,5 3 0,4 3 0,3 2 III BTD ...
... m nnnnm Axxx Axxx M Axxx éù êú êú = êú êú ëû MMMMM * max min iij j iij j xx xx - = = * * 1 * * () () () max () n iij ji i ii iij ji i ii xx Sw xx xx Rw xx - = - - = å - éù - = êú - êú ëû ** () () (1) ()() j j ss RjR Qvv ssRR - - -- - - =+- -- * * min;max min;max ...Marko Lazić, Filip Miletić, Milena Lekić, Veljko Rupar, Željko Petrović, Lazar Žujović . "Eksploatacioni učinci ugljenih sistema na površinskom kopu Tamnava–Zapadno polje" in 10th International Conference Coal 2021, Jugoslovenski komitet za površinsku eksploataciju, Zlatibor (2021)
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Equilibrium and kinetic studies of the reactions between [Ru(terpy)(bipy)Cl]Cl complex and biologically important N-donor ligands
Studije u oblasti antikancerogenih karakteristika jedinjenja rutenijuma(III/II) izazivaju veliku pažnju već nekoliko godina otkako su neka od njih kao što su KP1019 (indazolijum-tetrahloridobis(H-indazol)rutenat(III)) i NAMI-A (imidazolijum) -trans-tetrahlorido(dimetilsulfoksid)indazolerutenat(III)) dostigao nivo kliničkog ispitivanja. Kompleksi rutenijuma u reakciji sa molekulom DNK formiraju prvenstveno gvanin- i adenin-adukt, kao komplekse platine. Takođe, nekoliko studija ukazuje na veoma jake interakcije sa proteinima. Međutim, kompleksi Ru(III/II) pokazuju generalno manje toksične efekte od lekova platine(II).1 Proučavali smo kinetiku reakcija supstitucije kompleksa [Ru(terpi)(bipi)Cl]Cl sa biološki važnim ligandima: dimetilsulfoksidom, gvanozin-5’-monofosfatom, ...Aleksandar Mijatović, Biljana Petrović, Ratomir Jelić, Živadin Bugarčić. "Equilibrium and kinetic studies of the reactions between [Ru(terpy)(bipy)Cl]Cl complex and biologically important N-donor ligands" in EuroAnalysis 16 - Challenges in Modern Analytical Chemistry, Belgrade : Division of Analytical Chemistry of the Serbian Chemical Society (2011)
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Structure, interaction with biomolecules, and cytotoxicity of copper (II) complexes chelating some Schiff base ligands
Aleksandar Mijatović, Angelina Z. Caković, Aleksandar Lolić, Olivera Klisurić, Marko N. Živanović, Dragana S. Šeklić, Snežana Sretenović, Marija Ilić, Jovana Bogojeski (2023)Cancer remains one of the world's deadliest diseases, claiming many lives each day. Transition metal complexes are leading candidates in developing anticancer agens with cisplatin used in chemotherapy worldwide. Copper, an endogenous metal in the human body, is especially attractive because of its typical redox biological activities and a relatively strong affinity to nucleobases. A series of Cu(II) complexes with ethane-1,2-diamine as the amine part and pentane-2,4-dione and/or 1-phenylbutane-1,3-dione, pentane-2,4-dione and/or 1,1,1- trifluoropentane-2,4-dione, or 1,1,1-trifluoropentane-2,4-dione and/or 1-phenylbutane-1,3-dione as the ...Aleksandar Mijatović, Angelina Z. Caković, Aleksandar Lolić, Olivera Klisurić, Marko N. Živanović, Dragana S. Šeklić, Snežana Sretenović, Marija Ilić, Jovana Bogojeski. "Structure, interaction with biomolecules, and cytotoxicity of copper (II) complexes chelating some Schiff base ligands" in Applied Organometallic Chemistry, Wiley (2023). https://doi.org/10.1002/aoc.7253