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135 items
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Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes
Reakcije supstitucije monofunkcionalnih kompleksa [(TLtBu)PdCl]+ i [Pd(tpdm)Cl]+, gde je TLtBu = 2,6-bis[(1,3-di-terc-butilimidazolin-2-imino)metil]piridin i tpdm = terpiridindimetan, sa nukleofilima kao što su: tiourea, I−, Br−, NO2−, piridin i dimetil-sulfoksid (DMSO) proučavani su u 0,1 M vodenom rastvoru NaClO4 u prisustvu 10 mM NaCl. Reakcije su sprovedene na tri različite temperature (288, 298 i 308 K) korišćenjem tehnike zaustavljenog protoka na različitim temperaturama. Reakcije supstitucije su praćene pod uslovima pseudo prvog reda sa velikim viškom nukleofila. Dobijeni rezultati pokazuju da kompleks ...... this ion is also ‘‘soft’’ base, but less ‘‘soft’’ than iodide. This is the main reason for the lower reactivity of bromide. Since NO2 � ion is a ‘‘transition hard-soft’’ base, we expected and observed lower reactivity compared to that of halide + NPd Cl N N [Pd(tpdm)Cl] + N NN N N N NPd Cl ...
... [31], so this ion is also “soft” base, but less “soft” than iodide. This is the main reason for the lower reactivity of bromide. Since NO2 ion is a “transition hard-soft” base, we expected and observed lower reactivity compared to that of halide [(X)PdCl]* +L = [(X)PdL* + Cr 1 X=TL ®, tpdm L= thiourea ...Aleksandar Mijatović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić. "Substitution reactions of some novel sterically hindered monofunctional Pd(II) complexes" in Inorganica Chimica Acta, Elsevier BV (2011). https://doi.org/10.1016/j.ica.2011.11.031
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Pleistocene rhinoceros from Bogovina Cave: the first report of Stephanorhinus hundsheimensis Toula, 1902 (Mammalia, Rhinocerotidae) from Serbia
Finds of Pleistocene rhinoceros are rare in Serbia, and only one species (the woolly rhinoceros Coelodonta antiquitatis Blumenbach, 1799) has been reported so far. The current paper presents the dental material of an extinct so-called Hundsheim rhinoceros, Stephanorhinus hundsheimensis Toula, 1902 from Bogovina Cave (East ern Serbia). Both the morphological and metric characteristics of the teeth are consis tent with the attribution to S. hundsheimensis. Unfortunately, the rhinoceros material originated from an uncertain geological context, so there is no ...... Etruscan rhinoceros, S. etruscus Falconer, 1868 from the Early Villafranchian to Early Gale- rian (i.e., latest Pliocene to Early–Middle Pleisto- cene transition; Pandolfi et al., 2017a), the narrow- nosed rhinoceros, S. hemitoechus Falconer, 1859 from the Middle Galerian and Aurelian (i.e., Middle to Late ...
... Abhandlungen, 247(3):325-333. https://doi.org/10.1127/0077-7749/2008/0247-0325 Bona, F. and Sala, B. 2016. Villafranchian-Galerian mammal faunas transition in South-Western Europe. The case of the late Early Pleistocene mammal fauna of the Frantoio locality, Arda River (Castell’Arquato, Piacenza, Northern ...
... Raineri, G. 2016. Insights on the opening of the Galerian mammal migration pathway from magnetostratigraphy of the Pleistocene marine-continental transition in the Arda River section (northern Italy). Quaternary Research, 86:220-231. https://doi.org/10.1016/ j.yqres.2016.07.006 Musil, R. 1969. Die ...Predrag Radović, Miloš Radonjić, Emmanuel Billia. "Pleistocene rhinoceros from Bogovina Cave: the first report of Stephanorhinus hundsheimensis Toula, 1902 (Mammalia, Rhinocerotidae) from Serbia" in Palaeontologia Electronica, Coquina Press (2020). https://doi.org/10.26879/985
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Demise of the Wetterstein Carbonate Platform and onset of the Dachstein Carbonate Platform recorded in deep-water successions of the East Bosnian-Durmitor megaunit (Pliješevina, northern Montenegro, Dinarides)
Milica Mrdak, Eva Wagerer, Milan Sudar, Nevenka Djerić, Martin Đaković, Hans-Jürgen Gawlick. "Demise of the Wetterstein Carbonate Platform and onset of the Dachstein Carbonate Platform recorded in deep-water successions of the East Bosnian-Durmitor megaunit (Pliješevina, northern Montenegro, Dinarides)" in Geologica Carpathica, Central Library of the Slovak Academy of Sciences (2024). https://doi.org/10.31577/GeolCarp.2023.26
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Numerical modeling of Selanac debris flow propagation using SPH code
The Selanac debris flow is a very huge event triggered after extreme rainfall caused by Cyclone Tamara activity in the Republic of Serbia in May 2014. The Selanac case study was already modelling in different programs using Voellmy rheology assumptions like RAMMS software. In this paper research are focusing particularly on the process of debris flowing from initiation zone to main deposition area using Geoflow SPH two-phase model considering frictional rheology law. Main rheological parameters are back-calculated using also ...... heterogeneous and multiphase moving mass as a single-phase continuum. The others are considering two phases, solid and liquid, i.e. a granular skeleton with voids filled with either water or mud. If the shear resistance of the fluid phase can be neglected, the stress tensor in the mixture can ...
... calculation of pore water pressures propagation is possible to be obtained using Finite Difference Method coupled with two- phase model. Herein, just results of two-phase model propagation will be presented. The main equations are discussed by Pastor et al. (2009) considering: A. balance of mass ...
... Development of the Republic of Serbia. 7 REFERENCES Chen, C. and Ling, C.H. (1996). ‘’Granular-Flow Rheology: Role of Shear-Rate Number in Transition Regime’’. J. Eng. Mech. 122:469–480. Cuomo, S., Pastor, M., Cascini, L. and Castorino, G.C. (2014). “Interplay of Rheology and Entrainment in ...Jelka Krušić, Biljana Abolmasov, Miloš Marjanović, Manuel Pastor, Saeid M. Tayyebi . "Numerical modeling of Selanac debris flow propagation using SPH code" in SCG-XIII International Symposium on Landslides. Cartagena, Colombia- February 22-26, 2021, International Society for Soil Mechanics And Geotechnical Engineering (2021)
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Tectonic evolution of the Vršac Mts. (NE Serbia): Inferences from field kinematic and microstructural investigations
The Vršac Mts. in NE Serbia represent the key area to investigate structural relations between the Northern Serbo-Macedonian Subunit and Supragetic Unit of the Dacia Mega-Unit. The geodynamic events during the Variscan orogeny in the Late Paleozoic colligated the two units and led to their metamorphic differentiation. The Late Cretaceous extension exhumed the medium-grade Serbo-Macedonian metamorphic rocks and structurally juxtaposed them against the low-grade metamorphosed basement of the Supragetic Unit along an E-dipping shear zone, which outcrops in the ...severna srpsko-makedonska subjedinica, supragetikum, kinematska analiza, multifazna ekstenzionalna deformacija... quartzites, amphibo- lites, and marbles, intruded in the north-west by a Paleozoic age granitic body (Fig. 3). Towards the east these show gra- dual transition through the zone of retromorphosed albite gneisses that are, again, juxtaposed to albite-muscovite schists, chlorite-sericite schists, quartzites ...
... pressure is estimated at around 0.3 GPa. Interpretation and discussion The results of our kinematic and petrological investigations infer sharp transition between the medium-grade Serbo- Macedonian gneisses in the footwall and low-grade green- schists of the Supragetic Unit in the hanging-wall of the ...
... medium-grade crystalline basement of the Serbo-Macedonian Unit from below the low- grade metamorphic rocks of the Supragetic Unit. The follo- wing phase of the latest Cretaceous–Paleogene collision thrusted Europe-derived continental units W-ward over the Late Cretaceous to Paleogene Sava trench turbidites ...Uroš Stojadinović, Nemanja Krstekanić, Bojan Kostić, Marija Ružić, Aleksa Luković . "Tectonic evolution of the Vršac Mts. (NE Serbia): Inferences from field kinematic and microstructural investigations" in Geologica Carpathica, Central Library of the Slovak Academy of Sciences (2021). https://doi.org/https://doi.org/10.31577/GeolCarp.72.5.3
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Influence of mono- and two-component organic modifiers on determination of lipophilicity of tetradentate Schiff bases
Ispitivani su uticaji primene mono- i dvokomponentnih organskih modifikatora na određivanje lipofilnosti 12 tetradentatnih Šifovih baza metodom reverzno-fazne tankoslojne hromatografije. Osnovni cilj je da se proceni tip interakcije između posmatranih jedinjenja i komponenti primenjenih hromatografskih sistema i uspostavi neki obrazac ponašanja kako bi se lakše izabrala kombinacija organskih modifikatora koji će simulirati interakciju u biološkim sistemima na osnovu činjenica da iste osnovne intermolekularne interakcije su odgovorne za ponašanje supstanci i u biološkom i u hromatografskom sistemu. Primenjeni organski modifikator ...Nikola Stevanović, Aleksandar Mijatović, Aleksandar Lolić, Mario Zlatović, Rada Baošić. "Influence of mono- and two-component organic modifiers on determination of lipophilicity of tetradentate Schiff bases" in Chemical Papers, Springer Science and Business Media LLC (2021). https://doi.org/10.1007/s11696-021-01884-5
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Microstructural and magnetic properties of electrospun hematite/cuprospinel composites
Phase composition, microstructural and magnetic properties of electrospun hematite/cuprospinel composites were investigated. Samples were synthesized starting with 0 to 10 mol% of copper relative to iron. The round shape of reference electrospun fbres was preserved upon their heating up to 600 °C in air, whereas at 700 °C hollow substructure was additionally formed. In these reference samples the presence of hematite phase was detected by XRPD. A small amount (traces) of Fe3O4 /γ-Fe2O3 was also found, due to the ...Electrical and Electronic Engineering, Condensed Matter Physics, Atomic and Molecular Physics and Optics, Electronic, Optical and Magnetic MaterialsMira Ristić, Aleksandar Kremenović, Michael Reissner, Željka Petrović, Svetozar Musić. "Microstructural and magnetic properties of electrospun hematite/cuprospinel composites" in Journal of Materials Science: Materials in Electronics, Springer Science and Business Media LLC (2020). https://doi.org/10.1007/s10854-020-03526-0
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Long-term planning methodology for improving wood biomass utilization
The insufficiently developed forest management system is often followed by undeveloped forest resources supply chain and insufficient institutional support. These cause inefficient usage of fuel-wood as well as huge amounts of unused forest residues. In order to achieve optimal and long-term sustainable utilisation of biomass, an original methodology based on the interaction of mathematical optimization and backcasting approach has been developed. Mathematical optimization is used for both generation and consideration of techno-economic parameters of the forest biomass supply chain. ...Vladimir Vukašinović, Dušan Gordić, Marija Živković, Davor Koncalović, Dubravka Živković. "Long-term planning methodology for improving wood biomass utilization" in Energy, Elsevier BV (2019). https://doi.org/10.1016/j.energy.2019.03.105
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Electronic Dictionaries - from File System to lemon Based Lexical Database
In this paper we discuss some well-known morphological descriptions used in various projects and applications (most notably MULTEXT-East and Unitex) and illustrate the encountered problems on Serbian. We have spotted four groups of problems: the lack of a value for an existing category, the lack of a category, the interdependence of values and categories lacking some description, and the lack of a support for some types of categories. At the same time, various descriptions often describe exactly the same ...... simple textual file. This file was the base for the cre- ation of a dictionary of markers, that is, data categories and their values (Figure 1). Transition to the database that sup- ports the control of field domains revealed inconsistencies among markers: same markers used for different purposes, different ...
... existing tool for dictionary management LeXimir, in order to sup- port parallel development for a certain period of time, and to enable smooth transition of development environment. The database contains all currently used markers, but these markers have not a “flat” structure anymore, but rather ...
... but the use of triple-stores, e.g. graph databases Neo4J and DBGraph, is being investigated. The use of triple-stores will be read-only in this phase of de- velopment, and they will be used for querying and link- ing to external resources, while CRUD (create, read, up- date, delete) operations ...Ranka Stanković, Cvetana Krstev, Biljana Lazić, Mihailo Škorić. "Electronic Dictionaries - from File System to lemon Based Lexical Database" in Proceedings of the 11th International Conference on Language Resources and Evaluation - W23 6th Workshop on Linked Data in Linguistics : Towards Linguistic Data Science (LDL-2018), LREC 2018, Miyazaki, Japan, May 7-12, 2018, European Language Resources Association (ELRA) (2018)
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Back-arc underplating provided crustal accretion affecting topography and sedimentation in the Adria microplate
Paolo Mancinelli, Vittorio Scisciani, Cristina Pauselli, Gérard M. Stampfli, Fabio Speranza, Ivana Vasiljević (2021)Supported by evidence of deep crustal sources for the observed magnetic anomalies in Central Italy and by outcropping gabbros in the Croatian archipelago, we model the observed gravity and magnetic anomalies in the Central Adriatic Sea and surroundings. We suggest that the major magnetic anomalies in the area are related to a wide underplating and propose that this volume represents the first stage of the back-arc Adria continental breakup in Early Permian times. During the Palaeotethys-Adria collision, underplating has ...Paolo Mancinelli, Vittorio Scisciani, Cristina Pauselli, Gérard M. Stampfli, Fabio Speranza, Ivana Vasiljević. "Back-arc underplating provided crustal accretion affecting topography and sedimentation in the Adria microplate" in Marine and Petroleum Geology, Elsevier Ltd. (2021). https://doi.org/10.1016/j.marpetgeo.2021.105470
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Assessments of effects of implementation of strategic plans for development of Belgrade District heating system
The district heating system (DHS) is one of the key elements of the Belgrade energy system. Overview of the current state and basic characteristics of the DHS are presented in this paper. The focus is on the planned development of DHS and on the analyses of effects of realization of measures and projects defined by strategic documents related to DHS which are adopted by city authorities (Development Strategy of DHS and Strategy of Belgrade Development). Two exploratory scenarios were ...Dejan Ivezić, Marija Živković, Aleksandar Madžarević, Miodrag Grujić. "Assessments of effects of implementation of strategic plans for development of Belgrade District heating system" in Sustainable Cities and Society, Elsevier BV (2020). https://doi.org/10.1016/j.scs.2020.102304
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Sitni, ali bitni: uloga sitnih sisara, herpetofaune i mekušaca u rekonstrukciji pleistocenskih paleosredina
Fosilni ostaci životinja i biljaka imaju važnu ulogu u rekonstrukciji pleistocenskih paleosredina. U ovom radu opisan je značaj tri grupe životinja: sitnih sisara, herpetofaune I mekušaca. Mada je za rekonstrukciju važan sastav čitave asocijacije, nalasci pojedinih vrsta mogu biti dovoljno indikativni da otkriju tip staništa ili klimatske uslove. Posebnu teškoću pri rekonstrukciji paleosredina u Srbiji predstavlja činjenica da klimatske promene na Balkanskom poluostrvu nisu bile tako oštre kao u srednjoj i zapadnoj Evropi, pa ne postoji drastična razlika u ...... 139-151. . Montuire, S., (1999): Mammalian Faunas as Indicators of Environmental and Climatic Changes in Spain during the Pliocenc-Quaternary Transition. Quaternary Research, 52, 129-137. Montuire, S., & Desclaux, E., (1997): Palaeoecological analysis of mammalian faunas and environmental cvolution ...Katarina Bogićević, Draženko Nenadić, Dragana Đurić, Mihajlo Jovanović, Aleksandra Savković. "Sitni, ali bitni: uloga sitnih sisara, herpetofaune i mekušaca u rekonstrukciji pleistocenskih paleosredina" in Zbornik sažetaka III Kongresa geologa Bosne i Hercegovine, Neum, 21.-23.09.2023., Ilidža : Udruženje geologa Bosne i Hercegovine (2023)
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Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima
Aleksandar M. Mijatović, Jovana Bogojeski. "Supstitucione reakcije Pd(II) kompleksa sa biološki važnim biomolekulima" in Hemijski pregled, Srpsko hemijsko društvo (2017)
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Geodynamics of basins above subducted slabs: An integrated modelling study of tectonics, sedimentation, and magmatism in the Timok Magmatic Complex
Uros Stojadinovic, Marinko Toljic, Branislav Trivic, Radoje Pantovic, Danica Sreckovic-Batocanin, Nemanja Krstekanic, Bojan Kostic, Milos Velojic, Jelena Stefanovic, Nikola Randjelovic, Maja Males (2024)Uros Stojadinovic, Marinko Toljic, Branislav Trivic, Radoje Pantovic, Danica Sreckovic-Batocanin, Nemanja Krstekanic, Bojan Kostic, Milos Velojic, Jelena Stefanovic, Nikola Randjelovic, Maja Males. "Geodynamics of basins above subducted slabs: An integrated modelling study of tectonics, sedimentation, and magmatism in the Timok Magmatic Complex" in Annales geologiques de la Peninsule balkanique, National Library of Serbia (2024). https://doi.org/10.2298/GABP240116003S
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Utilizing sewage wastewater heat in district heating systems in Serbia: effects on sustainability
Marija Živković, Dejan Ivezić (2021)Transformation of the heating sector is recognized as being essential for ensuring reliable and afordable energy services provided with reduced consumption of energy sources and diminished impact on the environment and less import dependency. The possibility of utilizing energy sources that otherwise would be wasted needs to be considered and treated as a big advantage of district heating systems. Despite many advantages, sewage wastewater heat is still a mostly unused resource at the global level and a totally unused ...рекуперација топлоте из отпадних вода, систем даљинског грејања, топлотне пумпе, енергетске уштеде, емисија угљендиоксида, енергетска безбедност, Србија... approximately 75% of consumption in this sector (International Energy Agency 2014). Thus, the heat- ing sector has a decisive role in the energy transition to more sustainable energy systems. Transformation of the heating sector could substantially contribute to reaching goals of sustainable development ...
... energy services, provided with reduced consumption of energy sources, impact on the environment and import dependency (United Nations 2019). Transition to more sustainable systems can be achieved by acting on the demand and supply sides. In the previous period, much attention was paid to the demand ...
... data of existing facilities. However, in most of developing countries (such as Serbia) wastewater treatment plants are rare, or in the preparation phase, so presented methodologies cannot be applied. Although it is evident that utilization of renewable energy sources has a positive effect in mitigating ...Marija Živković, Dejan Ivezić. "Utilizing sewage wastewater heat in district heating systems in Serbia: effects on sustainability" in Clean Technologies and Environmental Policy, Springer Science and Business Media LLC (2021). https://doi.org/10.1007/s10098-021-02063-6
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Understanding partitioning of deformation in highly arcuate orogenic systems: Inferences from the evolution of the Serbian Carpathians
Nemanja Krstekanić, Liviu Matenco, Marinko Toljić, Oleg Mandić, Uroš Stojadinović, Ernst Willingshofer (2020)... defor- mation stages are specific to the studied area that relate in particular to multi-phase extension, strike-slip deformation and vertical axis rotations. 4.1. Cretaceous nappe emplacement The oldest phase of contraction led to the nappe emplacement of the Supragetic unit that was associated ...
... 2. The Eocene–Miocene orogen-parallel and perpendicular extension associated with large scale transcurrent motions The study area lies in the transition zone between orogen parallel and perpendicular extensions and strike-slip deformation that took place during the clockwise rotation of the Carpathians ...
... thrust (Fig. 4). Although the Cretaceous offset along the Supragetic thrust is difficult to estimate due to the absence of reliable markers, the transition from ductile to brittle deformation during thrusting indicates a minimum of 10–15 km offset. The youngest sedi- ments affected by this thrusting ...Nemanja Krstekanić, Liviu Matenco, Marinko Toljić, Oleg Mandić, Uroš Stojadinović, Ernst Willingshofer. "Understanding partitioning of deformation in highly arcuate orogenic systems: Inferences from the evolution of the Serbian Carpathians" in Global and Planetary Change, Elsevier BV (2020). https://doi.org/10.1016/j.gloplacha.2020.103361
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Environmental Energy Security Indicators as Tools for Environmental Protection
Еколошка прихватљивост је постала незаменљив синтезни показатељ сваке валидне енергетске анализе у последње две-три деценије. Енергетска безбедност је у директној хармонији с еколошком прихватљивошћу кроз многе прописане политичке циљеве, економске користи, правне тековине итд. Индикатори еколошке сигурности представљају један од основних елемената за одређивање енергетске безбедности и снажне алате за усмеравање енергетског сектора ка одрживом развоју. У овом раду, анализа је била концентрисана на показатеље енергетске безбедности у области животне средине који се односе на сектор природног гаса у ...енергетска безбедност, еколошки енергетски индикатори, заштита животне средине, еколошка прихватљивост... 2025, with the projections up to 2030 [5] and Program of implementation, energy security is defined as one of the basic cursors for ensuring the transition to sustainable energy development. Republic of Serbia is in the process of accession to the EU, with the status of a candidate country. Serbia ...
... monitoring. The data are then classified and fed into the analysis model itself in an adequate form. Such data are entered the synthesis model by the phase proposition procedure, where they are further classified and defined as the input data of the fuzzy set. At the same time, next step called ranking ...Aleksandar Madžarević, Dejan Ivezić, Marija Živković , Miloš Tansijević. "Environmental Energy Security Indicators as Tools for Environmental Protection" in Mining and Environmental Protection-MEP 2019, University of Belgrade, Faculty of Mining and Geology (2019)
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Sustainable Modularity Approach to Facilities Development Based on Geothermal Energy Potential
The study presented in this paper assessed the multidisciplinary approach of geothermal potential in the area of the most southeastern part of the Pannonian basin, focused on resources utilization. This study aims to present a method for the cascade use of geothermal energy as a source of thermal energy for space heating and cooling and as a resource for balneological purposes. Two particular sites were selected—one in a natural environment; the other within a small settlement. Geothermal resources come ...геотермална енергија, Панонски басен, геотермална каскада, енергетска ефикасност, бањски центри, балнеологија, биоклиматска архитектура, стратегије пасивног дизајнирања, модуларни објекти... resources [6–9]. Hot water springs have been used for healing and medical recovery since ancient times. Today, however, balneology is undergoing a transition both concerning its place in formal medical science and as an asset for the development of tourism, local and state economies and general popular ...
... resources [6-9]. Hot water springs have been used for healing and medical recovery since ancient times. Today, however, balneology is undergoing a transition both concerning its place in formal medical science and as an asset for the development of tourism, local and state economies and general popular ...
... strategies focused on a wide range of passive design measures that integrated the technology related to necessary active systems from the conceptual design phase. Water management in these facilities is very dependent on water composition, flow and temperature yet needs to be treated with extreme delicacy case ...Nataša Čuković-Ignjatović, Ana Vranješ, Dušan Ignjatović, Dejan Milenić, Olivera Krunić. "Sustainable Modularity Approach to Facilities Development Based on Geothermal Energy Potential" in Applied Sciences-Basel, МDPI (2021). https://doi.org/10.3390/app11062691
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A hundred years of Milutin Milanković's climate change theory - geological implications
Dejan Radivojević (2020)Миланковићева теорија циклуса објављена пре сто година је најважнија теорија у наукама које проучавају климу и имала је велики утицај на дисциплине које се баве Земљом. Ипак, његов рад је чекао више од педесет година да би добио потврду. Може се рећи да Миланковићев рад највећи утицај на геологију има у изради астрономске временске скале, подршци хипотези континенталног дрифта и палеоклиматологији. Добри резултати примене астрономске временске скале на неогене седименте иницирали су примену ове методе у мезозојским и у последње ...циклостратиграфија, астономска временска скала, геолошка временска скала, климатске промене, континентални дрифт... the first significant piece of evidence in defining the Paleozoic ATS, which is based on ab- solute time and thus connects the Paleozoic-Meso- zoic transition. Continental drift Even though Milanković and Wegener were not Earth scientists, they created two major scientific rev- olutions in geology which ...Dejan Radivojević. "A hundred years of Milutin Milanković's climate change theory - geological implications" in Geološki anali Balkanskoga Poluostrva, Univerzitet u Beogradu, Rudarsko geološki fakultet (2020). https://doi.org/10.2298/GABP201125011R
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Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)
Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik (2023)The behaviour and stability of arsenopyrite largely depend on its crystal structure, but studies of crystallography and structural defects are scarce. For clarification, we investigated a series of natural arsenopyrite crystals from the polymetallic Pb-Zn-(±Cu,Ag,Au,Sb,Bi,W) Šumadija-Kopaonik ore district (Serbia) by powder X-ray diffraction (XRPD). Among them, samples from the Drenjak gold mineralisation showed near-stoichiometric FeAsS composition and were further investigated by conventional and high-resolution transmission electron microscopy methods. TEM revealed abundant planar crystallographic defects and epitaxial surface oxide layer ...Inorganic Chemistry, Condensed Matter Physics,General Materials Science, General Chemical Engineering, crystal structure, FeAsS, oxidation, TEM, XRPD... topped by a ~1 nm amorphous layer (Figure 6a,b). The interface between pristine arsenopyrite and the surface layer is sharp, without any gradual transition that would sug;ggest intermediate metastable phases. According, to the EDS spot analysis, the crystalline layer is Fe- and As-rich oxide developed ...
... tion overview micrographs revealed numerous planar defects parallel to the (010) plane, accompanied by a large surrounding strain (Figure 3a). Phase-contrast TEM micrographs (HR-TEM) reveal a coherent crystal structure with subtle moirć superlattice fringes in (211), manifested as an enhanced ...
... types without any deviation compared to the bulk grain. Additionally, the SAED patterns recorded over the multiple lamellae correspond to a single-phase arsenopyrite-type structure (Figure 5b'). Other planar defects following, (22-1) planes (Figure 5c) can be interpreted as antiphase domains boundary ...Ivana Jelić, Aleksandar Pačevski, Aleksandar Kremenović, Aleš Šoster, Andreja Šestan, Janez Zavašnik. "Crystallography and Surface Oxidation of Stoichiometric Arsenopyrite from Šumadija-Kopaonik Pb-Zn/Polymetallic Ore District (Serbia)" in Crystals, MDPI AG (2023). https://doi.org/10.3390/cryst13020278