Претрага

Упит dcterms_subject_txt:Influence of synthesis method

2847 items

  • Human factor risk management procedures applied in the case of open pit mine

    Snežana Kirin, Aleksandar Sedmak, Wei Li, Miodrag Brzaković, Igor Miljanović, Ana Petrović, Simon Sedmak (2021)
    Risk management aims to provide a controlled work environment to ensure the safe operation of the high-risk systems. It is a dynamic process which work in a continual state of change. The issue of human factor risk and rules and regulations in open pit mine is a main focus of this paper in order to develop predictive models of behavior of workers in relation to compliance with the procedures and rules. Presented survey was conducted in open pit coal ...
    Upravljanje rizikom, ljudski faktor, bager sa kašikom, metod konačnih elemenata

  • Kinetics, mechanism, and equilibrium studies of the reactions between a ruthenium(II) complex and some nitrogen- and sulfur-donor nucleophiles

    Aleksandar M. Mijatović, Ratomir M. Jelić, Jovana Bogojeski, Živadin D. Bugarčić, Biljana Petrović (2013)
    Kinetika i mehanizam reakcija supstitucije između [Ru(trpi)(bpi)Cl]+ sa nukleofilima gvanozin-5′-monofosfatom, L-histidinom, tioureom i dimetilsulfoksidom proučavani su spektrofotometrijski u 0,1 M NaClO4 na 310 K. Red reaktivnosti za odabrane ligande je: tiourea > gvanozin-5′-monofosfat > L-histidin > DMSO. Ovaj red je povezan sa elektronskim, strukturnim i hemijskim karakteristikama kompleksa i nukleofila. Reakcija supstitucije sa tioureom je proučavana na tri različite temperature (288, 298 i 310 K). Negativna entropija aktivacije DS = potvrđuje asocijativni način aktivacije. Formiranje kompleksa [Ru(trpi)(bpi)H2O]2+ sa ligandima ...
    Kinetika, Ravnoteža, Ru(II), L-Histidin, Guanozin-5' -monofosfat, Dimetilsulfoksid, Tiourea
    ... 50-GMP. Finally, knowledge of the composition and stability of the species in the studied systems, especially at physiological pH, could contribute to a better understanding of some interactions in biological systems. Experimental RuCl3�xH2O, a starting salt for other synthesis, was pur- chased from ...
    ... determined by titration of 1.0, 1.5, and 2.0 mM solutions of [Ru(tr- py)(bpy)H2O] 2? with NaOH. The acid-base chemistry was characterized by fitting the potentiometric data to various acid-base models. The best model, selected according to the above-mentioned method of calculation, was consistent ...
    ... determined by titration of 1.0, 1.5, and 2.0 mM solutions of [Ru(tr- py)(bpy)H,O]?* with NaOH. The acid-base chemistry was characterized by fitting the potentiometric data to various acid-base models. The best model, selected according to the above-mentioned method of calculation, was consistent with the ...

  • Application of ERT in the study of debris-flow source area: Case study Selanac debris flow

    Dragana Đurić, Jelka Krušić, Biljana Abolmasov (2021)

  • Split-Desktop software for the analysis of fragment size distribution of blasted rock mass

    Milanka Negovanović, Lazar Kričak, Stefan Milanović, Jovan Marković, Nikola Simić, Snežana Ignjatović (2023)
    Drobljenje stena je najvažniji pokazatelj u proceni efekata miniranja pri proizvodnom miniranju u površinskoj eksploataciji. Stepen drobljenja stena ima veliki uticaj na efikasnost daljih operacija utovara, transporta, drobljenja i mlevenja. Optimalno drobljenje stena pri proizvodnom miniranju utiče na smanjenje ukupnih troškova proizvodnje. Stoga je pouzdana procena veličine drobljenja odminirane stenske mase veoma važno pitanje, ne samo u operacijama miniranja, već i u rudarskoj proizvodnji. Za predviđanje distribucije veličine komada odminirane stenske mase postoje različiti empirijski modeli. KUZ-RAM model omogućava ...
    Split-Desktop softver, drobljenje stena, miniranje, analiza, digitalna obrada fotografija

  • Prioritization of strategic measures for strengthening the security of supply of the Serbian natural gas sector

    Boban Pavlović, Dejan Ivezić, Marija Živković (2020)
    To strengthen the security of supply of the Serbian gas sector, it is necessary to analyze the impact of planned strategic measures. The analysis involves the identification of the most influential threats to the security of natural gas supply and prioritization of the strategic measures for overcoming the consequences of threats. The proposed methodology is based on Fuzzy Analytic Hierarchy Process. The obtained weights for the identified threats and strategic measures are formed according to experts' judgments. The results ...
    Sigurnost snabdevanja, Donošenje odluka, Snabdevanje prirodnim gasom, Fazi AHP, Energetski indikatori

  • Freeze-dried nanocrystal dispersion of novel deuterated pyrazoloquinolinone ligand (DK-I-56-1): Process parameters and lyoprotectant selection through the stability study

    Jelena R. Mitrović, Maja Bjelošević Žiberna, Aleksandar Vukadinović, Daniel E. Knutson, Dishary Sharmin, Aleksandar Kremenović, Pegi Ahlin Grabnar, Odon Planinšek, Dominique Lunter, James M. Cook, Miroslav M. Savić, Snežana D. Savić (2023)
    Recently, nanocrystal dispersions have been considered as a promising formulation strategy to improve the bioavailability of the deuterated pyrazoloquinolinone ligand DK-I-56-1 (7‑methoxy-2-(4‑methoxy-d3-phenyl)-2,5-dihydro-3H-pyrazolo[4,3-c]quinolin-3-one). In the current study, the freeze-drying process (formulation and process parameters) was investigated to improve the storage stability of the previously developed formulation. Different combinations of lyoprotectant (sucrose or trehalose) and bulking agent (mannitol) were varied while formulations were freeze-dried under two conditions (primary drying at -10 or -45 °C). The obtained lyophilizates were characterized in terms ...
    Pharmaceutical Science
    ... concentrations. The type and concentration of these excipients have been shown to have a strong influence on redispersibility (Jakubowska et al., 2022), so screening of lyoprotectants was the first step of the preliminary study. The formu- lation of interest in this research is intended for parenteral ...
    ... DK-I-56-1 was selected as the lead ligand for future studies based on its good phar- macological profile and relative ease of synthesis (Knutson et al., 2018). Due to low solubility of DK-I-56-1 in water as well as in many commonly used oils, co-solvents, and organic solvents, nanocrystal dispersion ...
    ... to a shift in the wavenumber of the OH-stretching band (Sri- tham and Gunasekaran, 2017), the moisture content was similar in all samples (about 3%), so its influence could be excluded when comparing different freeze-dried samples. The FT-IR spectrum of trehalose dihydrate in bulk was typical ...

  • Multiple-Criteria Decision-Making in Mine Development Planning

    Sanja Bajić (2023)
    The Borska Reka ore deposit is an experimental location where developed methodologies have been applied. It is the largest ore body within the Bor mining complex, which has been the subject of numerous studies and analyses for more than three decades. The paper focuses on the application of FAHP and the VIKOR method to address ranking of alternatives and select the optimal mining method by means of fuzzy multicriteria optimization.

  • Properties of fly ash and slag from the power plants

    Miloš Šešlija, Aleksandra Rosić, Nebojša Radović, Milinko Vasić, Mitar Đogo, Milovan Jotić (2016)
    This paper describes the physical, chemical and mineral properties of ash and slag, which were taken from thermal power plants Nikola Tesla A, Nikola Tesla B, Kostolac A and Kostolac B. The knowledge of the mineralogical material composition is important because the type of minerals directly determines the properties of the fly ash and slag and their possible application. Laboratory tests showed that ash and slag samples consist of the following minerals: amorphous materials, quartz, feldspar, mullite, melilite, cristobalite, ...
    fly ash, slag, physical composition, chemical composition, mineral composition, X-ray diffraction method
    ... Thesis, Faculty of Sciences, University of Niš, 38 p. EN 451-2 (1994): Method of testing fly ash – Part 2: Determination of fineness by wet sieving. EN 933-1 (1997): Tests for geometrical properties of aggregates – Part 1: Determination of particle size distribution – Sieving method. EN 1097-7 (1999): ...
    ... Mineralogical sample properties of the fly ash and slag from PPNT A, PPNT B, PPKO A and PPKO B were determined by X-ray examinations. X-ray diffraction is a non-destructive ex- perimental method based on the diffraction of X-rays withcrystal lattice sized wavelengths. This method is primarily used for qual- ...
    ... samples (Table 3) by the X-ray diffraction method it can be observed that: • all samples of ash contain a significant amount of amor- phous material (AM); • samples of ash from Obrenovac include quartz (Q) and feld- spar (f) as the most common minerals, while the other iden- tified minerals are ...

  • Single and multi-phase inclusions in garnets from the Lešnica alluvion in the Internal Dinarides, Serbia

    Maja Milošević, Bojan Kostić (2021)
    ... varioustypes of inclusions in their structure. Single and multiphase inclusions in the garnets wereexamined optically by petrographic methods followed by SEM-EDS method, applied for thechemical analyses of the individual inclusion, and LA-ICP-MS applied to determine distribution andcontent of trace elements ...
    ... elements in the host garnet. Results from SEM-EDS method show that garnets are of the spessartine-almandine type with theincorporation of irregular inclusions determined as rare earth elements (REE) minerals (monazite,xenotime, columbite-tantalite) and accessory minerals that usually incorporate REE (titanite ...
    ... радовима запослених доступним у слободном приступу. - Претрага репозиторијума доступна је на www.dr.rgf.bg.ac.rs The Digital repository of The University of Belgrade Faculty of Mining and Geology archives faculty publications available in open access, as well as the employees' publications. - The Repository ...

  • Флотабилност халкопирита из полиметаличне руде рудника „Рудник”

    Ђурица Н. Никшић (2022)
    The doctoral dissertation Chalcopyrite flotability from polymetallic "Rudnik" mine ore consists of two parts. The first part is a general part in which the theoretical foundations of the flotation concentration process, the flotation properties of chalcopyrite, the influence of certain flotation reagents and the mechanism of action on the flotation properties of chalcopyrite are presented. This part also describes the process of flotation concentration of polymetallic ore from the "Rudnik" mine. The second part is ...
    Халкопирит, флотацијска концентрација, KAX, NaCN, pH пулпе

  • Determining the Groundwater Balance and Radius of Influence Using Hydrodynamic Modeling: the Case Study of the Groundwater Source “Šumice” (Kikinda, Serbia)

    Dušan Polomčić, Dragoljub Bajić, Jelena Zarić (2015)
    A groundwater flow model was developed to simulate groundwater extraction from the public water supply source of the City of Kikinda. The hydrodynamic model includes the municipal groundwater source of Kikinda (Šumice and the Jezero Well), but also an extended area where there are groundwater sources that provide water supply to three factories: (MSK, TM and LŽT - Kikinda). Hydrodynamic modeling, based on the numerical method of finite differences will show the groundwater balance of the sources in the ...
    Water supply, Aquifer, Flow, Groundwater regime, Numerical modeling, Particle tracking
    ... negligible order of magnitude of dispersion effects), the particle tracking method for the determination of the radius of influence of the groundwater source was used and presented. The maximum well discharge capacity of Šumice was found to be 117.66 l/s, at which the radius of influence of Šumice was ...
    ... based on the numerical method of finite differences will show the groundwater balance of the sources in the extended area of Kikinda. The impact of the industrial water sources on the regime of the public water supply source will also be assessed. The radius of influence of the groundwater source ...
    ... The groundwater balance of the groundwater sources was determined by hydrodynamic modeling. The impact of industrial groundwater sources on the municipal groundwater source was also assessed. The particle tracking method [12] was used to determine the radius of influence of the groundwater sources ...

  • Дефинисање археолошких објеката на локалитету Кремените њиве применом Ојлерове 3Д деконволуције на магнетометријске податке

    Весна Цветков, Илија Васиљевић, Бранислав Сретеновић, Весна Дамњановић (2018)
    ... in the analytical signal network. Such a method of detection of  peaks can be used to estimate the depth to the upper surface of the source of anomalies.  Based on the results of the test on synthetic data, for the calculation of the depth to the source  of the magnetic anomalies at the site Kremen ...
    ... anomalous  zone.  Here  the  positions  of  Euler's  solutions  have  quite well  outlined  the  edges  of  the  741 sources of anomalies. Expected depths to the upper boundary of the sources of anomalies are between  0.4 and 0.6 [m].  The choice of the O3DD method itself is reduced to a subjectiv ...
    ... or gives the exact positions of the edges of the source, while with the Standard Method  the area covered by solutions is somewhat broader.  In the case of deeper sources, it was necessary to change the value of the structural index for a  more accurate determination of the depth. The Standard O3DD ...

  • A tool for identifying the criticality in the disordered systems with metastable dynamics

    Svetislav Mijatović, Dragutin Jovković, Sanja Janićević, Stefan Graovac, Đorđe Spasojević (2021)
    Физика кондензоване материје

  • Low-temperature phase transition and magnetic properties of K3YbSi2O7

    Predrag Dabić, Volker Kahlenberg, Biljana Krüger, Marko Rodić, Sabina Kovač, Jovan Blanuša, Zvonko Jagličić, Ljiljana Karanović, Václav Petříček, Aleksandar Kremenović (2021)
    alkalni silikati elemenata retkih zemalja, fazni prelazi, magnetne karakteristike, razdvajanje kristalnog polja, silikati lantanica
    ... magnetic properties of K3YbSi2O7 was examined. 2. Experimental 2.1. Synthesis and crystallization of K3YbSi2O7 Single crystals were obtained during a high-temperature flux synthesis experiment using 0.0942 g of a nutrient consisting of a mixture of Yb2O3 (Sigma-Aldrich, 99.99%) and SiO2 (Merck, ...
    ... magnetic properties of K;YbSi,0O7 was examined. 2. Experimental 2.1. Synthesis and crystallization of K;YbSi,O7 Single crystals were obtained during a high-temperature flux synthesis experiment using 0.0942¢ of a nutrient consisting of a mixture of Yb,O3 (Sigma-Aldrich, 99.99%) and SiO, (Merck, p.a.) in ...
    ... no apparent influence of the phase transformation on its magnetic properties. Analysis of the magnetization data revealed the positions of the three lowest crystal field levels of the Yb3+ cations, as well as the corresponding projections of their angular momentum on the direction of the magnetic ...

  • Hydrochemical changes and groundwater grouping data by multivariate statistical methods within one karst system: recharge–discharge zone (Eastern Serbia case study)

    Ljiljana Vasić, Dragana Živojinović, Vladana Rajaković-Ognjanović (2020)
    Geochemistry and Petrology

  • Inhibitory effect of platinum and ruthenium bipyridyl complexes on porcine pancreatic phospholipase A2

    Tina Kamčeva, Jörg Flemmig, Bojana Damnjanović, Jürgen Arnhold, Aleksandar Mijatović, Marijana Petković (2011)
    Fosfolipaza pankreasa A2 (PLA2) igra važnu ulogu u ćelijskoj homeostazi kao iu procesu karcinogeneze. Efekti metalo-lekova koji se koriste kao hemoterapeutici na aktivnost ovog enzima nisu poznati. U ovom radu, interakcija između PLA2 svinjskog pankreasa i dva odabrana kompleksa prelaznih metala — tetrahloro(bipiridin) platine(IV) ([PtCl4(bipi)]) i dihloro (bipiridin) rutenijum(III)hlorida ([RuCl2(bipi)2) ]Cl)—proučavana je. Laserska desorpcija/jonizacija uz pomoć matriksa, vremenska masa spektrometrija (MALDI-TOF MS) i fluorescentna spektroskopija korišćeni su za analizu aktivnosti enzima u odsustvu i prisustvu metalnih kompleksa i za ...
    Metals and Alloys, Biochemistry, Biomaterials, Biophysics, Chemistry (miscellaneous)
    ... powerful technique for the analysis of bipyridine metal complexes,27 and therefore it is used here as a method of first choice. Tested metal complexes affect the enzymatic aLaboratory of Physical Chemistry, Institute of Nuclear Sciences ‘‘Vinča’’, University of Belgrade, Mike Petrovića Alasa 12-14 ...
    ... interaction of these metallo-drugs with enzymes involved in phospholipid metabolism. Although metal complexes are efficient anti- proliferative agents in solid tumors, there are numerous side effects of these drugs such as nephrotoxicity and tumor cell resistance that must be overcome by synthesis of new ...
    ... a suitable method for sensitive detection of the PLA2 activity.31 We selected this approach for monitoring concen- tration changes of LPLs, as products of the PC digestion with PLA2 with and without metal complexes. Along with high sensitivity and possibility to acquire high number of information ...

  • Failure Estimation of the Majdanpek Open Pit East Face Based on Inverse Velocity Model

    Miloš Marjanović, Stefan Milanović, Nikola Simić, Lazar Kričak (2024)
    The Majdanpek open pit mine south district is currently active mining prospect of copper ore exploitation in eastern Serbia. Its depth is approaching the termination depth and occurrences of large-scale instabilities and global instability of the final pit slope is possible. These can generate catastrophic mass movement inside an area that encloses a regional road route and the Pek River bed which is channelled along the outer contour of the pit. The displacements that were noted in early 2023, in the ...
    displacement, survey, inverse velocity, open pit

  • Kristalografsko proučavanje strukturne desimetrizacije granata grosularsko-andraditske izomorfne serije

    Pavle I. Tančić (2016-09-21)
    U ovoj Doktorskoj disertaciji proučavano je pet različitih zona makroskopski zonarnog grandita sa lokaliteta Meka Presedla (Kopaonik, Srbija). Pomoću hemijske i elektronske analize mikroprobe preračunati su relativno visoko homogeni sastavi zona, t.j.: Grs64±1Adr36±1Sps2 (A), Grs62±1Adr38±1Sps2 (B), Grs59±2Adr40±2Sps2 (C), Grs58±2Adr41±2Sps2 (D) i Grs58±1Adr41±1Sps2 (E). Glavne promene u sastavima izražene formulom: Ca2,93-2,97Mn0,05-0,06Mg0,00-0,01Al1,14-1,26Fe3+0,72-0,83Ti0,00-0,02Si2,97-3,02O12 ukazuju da je jedina značajnija varijacija ustanovljena samo kod Al-Fe3+ raspodela u oktaedarskom položaju. Ovakav hemijski sastav je potvrđen i sa matematičkim proračunima iz IC i Raman analiza. Urađena ...
    Macroscopically zoned grandite, chemical analysis, electron microprobe analysis, Raman, Rietveld, structure, dissymmetrization, space group

  • Razvoj integralnog modela za optimizaciju diskontinualnog sistema proizvodnje na površinskim kopovima nemetala

    Miodrag Čelebić (2024)
    Izbor optimalne mehanizacije u diskontinualnom sistemu transporta je jedna od najvažnijih odluka koju treba donijeti prilikom projektovanja površinskih kopova. Pri izboru optimalne mehanizacije, uticaj ima veliki broj faktora, kako prirodnih – geoloških i ekoloških, tako i tehničkih, ekonomskih i socijanih. Neki od njih se mogu izraziti numerički, u određenim mijernim jedinicama, a neki opisno, lingvističkim varijablama, shodno uslovima koji vladaju na rudnim ležištima, a koje karakterišu visok stepen neizvjesnosti i neodređenosti kako prilikom istraživanja, tako i tokom procesa eksploatacije ...
    izbor mehanizacije, tehnologija eksploatacije, diskontinualani sistem, ekspertsko odlučivanje, lingvističke varijable, MCDM, FAHP

  • A comparison between ARIMA, LSTM, ARIMA-LSTM and SSA for cross-border rail freight traffic forecasting: the case of Alpine-Western Balkan Rail Freight Corridor

    Miloš Milenković, Miloš Gligorić, Nebojša Bojović, Zoran Gligorić (2023)
    železnica, prekogranični teretni saobraćaj, ARIMA, LSTM, SSA